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微量の鉄(II)を含むアルカリ塩化物結晶のメスバウァー分光学的研究
https://fra.repo.nii.ac.jp/records/2011457
https://fra.repo.nii.ac.jp/records/201145748c2d437-729b-4a2e-8000-a95008a2766d
| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2024-10-11 | |||||
| タイトル | ||||||
| タイトル | 微量の鉄(II)を含むアルカリ塩化物結晶のメスバウァー分光学的研究 | |||||
| 言語 | ja | |||||
| タイトル | ||||||
| タイトル | Mossbauer spectroscopic study of alkali chloride crystals containing a small amount of iron (2) | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | departmental bulletin paper | |||||
| アクセス権 | ||||||
| アクセス権 | open access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
| 著者 |
甲斐, 徳久
× 甲斐, 徳久 |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | The behavior of a small amount of Fe2+ in the alkali chloride crystals was investigated mainly by the use of absorption Mössbauer spectroscopy. In cases of both lithium chloride and sodium chloride systems containing a small amount of iron (II), the single line absorption due to Fe2+ substituted for Li+ or Na+ was observed at room temperature. The assignment was also justified from the results obtained in Mössbauer spectrum measurements of both LiCl (57Fe) and NaCI (57Fe) systems containing about 0.1 atomic percent (abbreviated as at%) of enriched iron57(II). 60Co-Y ray irradiation experiments were also performed for the both systems to elucidate the interaction between Fe2+ and defects in the crystals, but irradiation effects were not observed. In cases of potassium chloride and rubidium chloride systems containing a small amount of iron(II), only one doublet absorption with the isomer shift characteristic of ionic ferrous ion was observed at room temperature. Each doublet absorption was interpreted as to be arisen from the K2FeCl, compound in case of potassium chloride system and the Rb2FeCl4 compound in case of rubidium chloride system, respectively. The assignment was also justified from the results obtained in X-ray diffraction and Mössbauer spectrum measurements of the potassium- and rubidium-chloroferrate compounds prepared in an electric furnace. 60Co-γ ray irradiation effects were not observed for the potassium- and rubidium-chloroferrate compounds. In case of cesium chloride system containing a small amount of iron (II), one doublet absorption with the isomer shift characteristic of ionic ferrous ion was observed only at liquid nitrogen temperature. The absorption was assigned to the Cs3FeCl5 compound from the results obtained in X-ray diffraction measurement of the cesium chloride system. | |||||
| 言語 | en | |||||
| 書誌情報 |
ja : 水産大学校研究報告 en : The Journal of the Shimonoseki University of Fisheries 巻 30, 号 1, p. 63-81, ページ数 19, 発行日 1981-11 |
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| 出版者 | ||||||
| 出版者 | 水産大学校 | |||||
| 言語 | ja | |||||
| 出版者 | ||||||
| 出版者 | the Shimonoseki University of Fisheries | |||||
| 言語 | en | |||||
| ISSN | ||||||
| 収録物識別子タイプ | PISSN | |||||
| 収録物識別子 | 0370-9361 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AN00124678 | |||||
| 情報源 | ||||||
| 識別子タイプ | Local | |||||
| 関連識別子 | fishu_k_30_63 | |||||
| 関連サイト | ||||||
| 識別子タイプ | URI | |||||
| 関連識別子 | https://agriknowledge.affrc.go.jp/RN/2010253638 | |||||
| 言語 | ja | |||||
| 関連名称 | 日本農学文献記事索引(agriknowledge) | |||||
